Hi Jean,
The mBot 101 is an customized robot, its Bluetooth doesn’t support mBlock APP. It only support mBlock software on PC to run program online.
Also, the mBlock doesn’t support upload program to mBot 101 no matter via the USB cable or Bluetooth. If you want to upload program to mBot 101, you can only do it via Arduino software.
If you have added the makeblock library for Arduino101/Genuino101 in the Arduino software, you can upload the example program DCMotor to the robot.
The example program DCMotor use the Port 9 and Port 10 for the motors, if you want to use the Port 2, you can change the Port 10 to Port 2.
@Andreas, it is so kind of you linking the instruction. Actually, the page 10 instruction is for standard mBot 1.1 robot. The robot Jean has is the customized robot mBot 101 which is different with mBot 1.1.