The IR remote uses the built-in IR Transmitter/Receiver so unless you reinstalled the default program, it won’t do anything (requires you to write a program to use it). I wrote an ebook about using mBlock with the mBot (STEM, not Ranger or Starter kits) that provides a really basic introduction to the devices on the mBot, including programming for the IR remote (link). There are also a lot of tutorials on the Makeblock Learning and Education sites that are helpful too.
One of the things that you will need to keep in mind is that you must connect to the mBot via the Connect menu and for me the bluetooth receiver appears as a serial port when I’m using it to send commands over the air (for what it’s worth, the same hold true for the WiFi module). If you are attempting to upload a program that allows the mBot to run autonomously, you’ll need to use the USB cable because the avrdude onboard programmer for the microcontroller cannot be access via Bluetooth* or WiFi*.
mBlock will only allow a single connection to the mBot, so if you are connected via Bluetooth on your mobile device, the mBlock instance on your PC cannot connect to it using the Bluetooth connection. This seems to trip up folks, but it’s the nature of a serial connection and will require you to drop the Bluetooth connection on one device so that another can connect.
Glad to help with any other questions.
* If you use a Bluetooth or WiFi dongle in the USB port, then of course this does not hold true.